HCID 73186002, compound → HCID 13638029, compound

HRID 1579981Notes

Reaction equation

HRID 1579981 reaction equation
[C:1]([C:3]([C:15]([O:17][CH3:18])=[O:16])=[N:4][C:5](C)=[C:6]([NH2:13])[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1)#[N:2].C(C(OC)=NC=C(N)C1C=CC=CC1=C=O)#N>>[CH3:18][O:17][C:15]([C:3]1[C:1]([NH2:2])=[N:13][C:6]([C:7]2[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=2)=[CH:5][N:4]=1)=[O:16]

Participants

3

Reactant 2

HCID 73186002HCID 73186002, compoundHCID 86732919HCID 86732919, compound

Product 1

HCID 13638029HCID 13638029, compound

Procedure

One operates as in Example 15, but the 4 parts of 1-cyano-1-methoxycarbonyl-3-methyl-4-amino-4-phenyl-2-aza-1,3-butadiene are replaced by 3.8 parts of 1-cyano-1-methoxy-carbonyl-4-amino-4-phenyl-2-aza-1,3-butadiene. 3.66 parts of 2-methoxycarbonyl-3-amino-5-phenyl-pyrazine are obtained. After recrystallisation of the product from methanol the melting point is 228°C.

Sources & evidence

ORD record
ord-94de2d1a489e40268c1a0c6724d97b0c
Source dataset
uspto-grants-1976_01
Patent number
US03932404

Reaction notes

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