HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium ethoxide → 2-Ethoxyphenyl methyl sulfide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium ethoxide | HCID 2723922 | — |
| Reactant | 2-Chlorophenyl methyl sulfide | HCID 2737363 | — |
| Catalyst | Copper | HCID 23978 | — |
| Solvent | Nitrobenzene | HCID 7416 | — |
| Product | 2-Ethoxyphenyl methyl sulfide | HCID 12772779 | — |
Reaction Steps
o-Chlorothioanisole (prepared by the procedure of Example 5-A (15.85 g., 0.1 mole) is stirred at reflux in nitrobenzene containing copper powder (100 mg.) and sodium ethoxide (6.8 g., 0.1 mole) for 2 hours. The product is steam distilled and the distillate dried and fractionally distilled under reduced pressure to yield o-ethoxythioanisole.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03932498 |
| Source dataset | uspto-grants-1976_01 |
| ORD ID | ord-46851fe63ae0435ebb2aa5d2c718cdbc |
| Source note | uspto-grants-1976_01 |