Phosphorus pentachloride → HCID 86732950, compound

HRID 1580454Notes

Reaction equation

HRID 1580454 reaction equation
P(Cl)(Cl)(Cl)(Cl)[Cl:2].[CH:7]([N:10]([CH:29]([CH3:31])[CH3:30])[CH2:11][CH2:12][O:13][C:14]1[C:27]2[C:26]3[C:21](=[CH:22][CH:23]=[CH:24][CH:25]=3)[C:20](=O)[NH:19][C:18]=2[CH:17]=[CH:16][CH:15]=1)([CH3:9])[CH3:8]>P(Cl)(Cl)(Cl)=O>[CH:7]([N:10]([CH:29]([CH3:31])[CH3:30])[CH2:11][CH2:12][O:13][C:14]1[C:27]2[C:18](=[N:19][C:20]([Cl:2])=[C:21]3[C:26]=2[CH:25]=[CH:24][CH:23]=[CH:22]3)[CH:17]=[CH:16][CH:15]=1)([CH3:9])[CH3:8]

Participants

4

Reactant 2

HCID 24819Phosphorus pentachlorideHCID 86732951HCID 86732951, compound

Product 1

HCID 86732950HCID 86732950, compound

Reagents, catalysts & solvents 1

HCID 24813Phosphorus oxychlorideSolvent

Procedure

Phosphorous pentachloride (173 mg., 0.83 mM), phosphorous oxychloride (80 ml.) and 3,8-bis[(β-diisopropylamino(ethoxy]-6(5H)-phenanthridinone (2.0 g., 4.15 mM) were reacted according to the procedure of Example VII to give 1.66 g. of the title product; M.P. 88° C.-91° C.

Workup

  1. customto give 1.66 g

Sources & evidence

ORD record
ord-389c1d910d0b4ebbba503a5205a96d66
Source dataset
uspto-grants-1976_01
Patent number
US03932643

Reaction notes

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