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HRID1580529

反应详情

EQUATION

反应方程式

HRID 1580529 的结构方程式

REACTANTS

反应物

2
结构：CN=C=O
HCID12228

Methyl isocyanate

C2H3NO

结构：CC(=O)c1cc(Cl)c(O)c([N+](=O)[O-])c1
HCID21561878

未命名化合物

PRODUCTS

生成物

1
结构：CNC(=O)Oc1c(Cl)cc(C(C)=O)cc1[N+](=O)[O-]
HCID21561896

未命名化合物

PROCEDURE

实验过程

A mixture of 21.5 grams (0.1 mole) 3'-chloro-4'-hydroxy-5'-nitroacetophenone and 85.0 milliliters (a large excess) of methylisocyanate was refluxed for 5 hours. On cooling, a white crystalline product was formed. The product was filtered (weight 18.0 grams, melting point 115°-118° C.) and was identified by characteristic peaks in the infrared spectrum as 3'-chloro-4'-(N-methylcarbamoyloxy)-5'-nitroacetophenone.

WORKUP

后处理

  1. temperaturewas refluxed for 5 hours
  2. temperatureOn cooling
  3. customa white crystalline product was formed
  4. filtrationThe product was filtered (weight 18.0 grams, melting point 115°-118° C.)