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HRID1581111

反应详情

EQUATION

反应方程式

HRID 1581111 的结构方程式

REACTANTS

反应物

2
结构：c1ccc(P(c2ccccc2)c2ccccc2)cc1
HCID11776

Triphenylphosphine

C18H15P

结构：CCCCC(CC)C(=O)CCl
HCID20300708

1-Chloro-3-ethylheptan-2-one

C9H17ClO

PRODUCTS

生成物

1
结构：CCCCC(CC)C(=O)C[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Cl-]
HCID21561484

未命名化合物

收率 129.9%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：ClC(Cl)Cl
溶剂HCID6212

Chloroform

CHCl3

PROCEDURE

实验过程

A solution of 1-chloro-3-ethyl-2-heptanone (88.4 g.) and triphenylphosphine (81 g.) in chloroform (100 ml.) was saturated with nitrogen and refluxed under nitrogen overnight. The chloroform was removed in vacuo to give crude 2-oxo-3-ethylheptyltriphenylphosphonium chloride (176.1 g.).

WORKUP

后处理

  1. temperaturerefluxed under nitrogen overnight
  2. customThe chloroform was removed in vacuo