Tert-Butyl hypochlorite → HCID 131710018, compound

HRID 1581129Notes

Reaction equation

HRID 1581129 reaction equation
[C:1]1([NH:7][N:8]=[C:9]([C:19](=[O:21])C)[C:10](=O)[CH2:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14]C=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Cl:22]OC(C)(C)C>C(Cl)(Cl)Cl>[C:1]1([NH:7][N:8]=[C:9]([CH2:10][C:11]2[CH:12]=[CH:17][CH:16]=[CH:15][CH:14]=2)[C:19]([Cl:22])=[O:21])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

4

Reactant 2

HCID 521297Tert-Butyl hypochloriteHCID 178468316HCID 178468316, compound

Product 1

HCID 131710018HCID 131710018, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

The foregoing procedure was repeated, but using 12.1 gms. 1-phenyl-2,3,4-pentanetrione-3-phenylhydrazone, 100 ml. chloroform, and 6 ml. tert-butyl hypochlorite. Upon recrystallization from 100 ml. methanol there was obtained 6.3 gms. of compound having a melting point at 132° to 134°C.

Workup

  1. customUpon recrystallization from 100 ml
  2. custommethanol there was obtained 6.3 gms
  3. customat 132° to 134°C.

Sources & evidence

ORD record
ord-94f8ef775779447085e47a917c30694f
Source dataset
uspto-grants-1976_01
Patent number
US03935316

Reaction notes

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