2-(2-Carbazol-9-yl-ethoxy)-ethanol → 2-[2-(9H-Carbazole-9-yl)ethoxy]ethanol 3,4,5-tris(5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heptadecafluorododecyloxy)benzoate

HRID 1582017Notes

Reaction equation

HRID 1582017 reaction equation
C1N([C@@H]2O[C@H](CO)[C@H](O)[C@H](O)[C@H]2O)N=NC=1COCC(N)(COCC1N=NN([C@@H]2O[C@H](CO)[C@H](O)[C@H](O)[C@H]2O)C=1)CO.[F:43][C:44]([F:141])([F:140])[C:45]([F:139])([F:138])[C:46]([F:137])([F:136])[C:47]([F:135])([F:134])[C:48]([F:133])([F:132])[C:49]([F:131])([F:130])[C:50]([F:129])([F:128])[C:51]([F:127])([F:126])[CH2:52][CH2:53][CH2:54][CH2:55][O:56][C:57]1[CH:58]=[C:59]([CH:63]=[C:64]([O:96][CH2:97][CH2:98][CH2:99][CH2:100][C:101]([F:125])([F:124])[C:102]([F:123])([F:122])[C:103]([F:121])([F:120])[C:104]([F:119])([F:118])[C:105]([F:117])([F:116])[C:106]([F:115])([F:114])[C:107]([F:113])([F:112])[C:108]([F:111])([F:110])[F:109])[C:65]=1[O:66][CH2:67][CH2:68][CH2:69][CH2:70][C:71]([F:95])([F:94])[C:72]([F:93])([F:92])[C:73]([F:91])([F:90])[C:74]([F:89])([F:88])[C:75]([F:87])([F:86])[C:76]([F:85])([F:84])[C:77]([F:83])([F:82])[C:78]([F:81])([F:80])[F:79])[C:60]([OH:62])=[O:61].[CH:142]1[C:154]2[N:153]([CH2:155][CH2:156][O:157][CH2:158][CH2:159]O)[C:152]3[C:147](=[CH:148][CH:149]=[CH:150][CH:151]=3)[C:146]=2[CH:145]=[CH:144][CH:143]=1>>[CH:151]1[C:152]2[N:153]([CH2:155][CH2:156][O:157][CH2:158][CH2:159][O:61][C:60](=[O:62])[C:59]3[CH:58]=[C:57]([O:56][CH2:55][CH2:54][CH2:53][CH2:52][C:51]([F:126])([F:127])[C:50]([F:128])([F:129])[C:49]([F:130])([F:131])[C:48]([F:132])([F:133])[C:47]([F:134])([F:135])[C:46]([F:136])([F:137])[C:45]([F:138])([F:139])[C:44]([F:140])([F:141])[F:43])[C:65]([O:66][CH2:67][CH2:68][CH2:69][CH2:70][C:71]([F:94])([F:95])[C:72]([F:93])([F:92])[C:73]([F:91])([F:90])[C:74]([F:89])([F:88])[C:75]([F:87])([F:86])[C:76]([F:85])([F:84])[C:77]([F:83])([F:82])[C:78]([F:81])([F:80])[F:79])=[C:64]([O:96][CH2:97][CH2:98][CH2:99][CH2:100][C:101]([F:124])([F:125])[C:102]([F:122])([F:123])[C:103]([F:120])([F:121])[C:104]([F:118])([F:119])[C:105]([F:117])([F:116])[C:106]([F:115])([F:114])[C:107]([F:113])([F:112])[C:108]([F:111])([F:110])[F:109])[CH:63]=3)[C:154]3[C:146](=[CH:145][CH:144]=[CH:143][CH:142]=3)[C:147]=2[CH:148]=[CH:149][CH:150]=1

Participants

4

Reactant 3

HCID 6574892-(2-Carbazol-9-yl-ethoxy)-ethanolHCID 113208743,4,5-Tris(5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heptadecafluorododecyloxy)benzoic acidHCID 86277907dendron D1

Product 1

HCID 227193042-[2-(9H-Carbazole-9-yl)ethoxy]ethanol 3,4,5-tris(5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heptadecafluorododecyloxy)benzoate

Procedure

The synthesis of a mobility donor fluorinated dendron D1 of the present invention is as shown in the Scheme below. D1 is prepared using 3,4,5-tris-(12,12,12,11,11,10,10,9,9,8,8,7,7,6,6,5,5-heptadecafluoro-n-dodecan-1-yloxy)-benzoic acid as a starting material. The intermediate is then reacted with an alcohol of the desired apex moiety, 2-(2-carbazol-9yl-ethoxy)-ethanol, to obtain the compound of the invention.

Workup

  1. customThe synthesis of a mobility donor
  2. customto obtain the compound of the invention

Sources & evidence

ORD record
ord-85717f65ccb4413d96d4b42780f39c8c
Source dataset
uspto-grants-2004_05
Patent number
US06733883B2

Reaction notes

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