Aluminium lithium hydride → HCID 69907539, compound

HRID 1582682Notes

Reaction equation

HRID 1582682 reaction equation
[H-].[H-].[H-].[H-].[Li+].[Al+3].[CH:7]1([C:13]2[CH:18]=[CH:17][C:16]([C:19]([CH3:26])=[CH:20][C:21](OCC)=[O:22])=[CH:15][CH:14]=2)[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1>C1COCC1>[CH:7]1([C:13]2[CH:14]=[CH:15][C:16]([C:19]([CH3:26])=[CH:20][CH2:21][OH:22])=[CH:17][CH:18]=2)[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12]1

Participants

4

Reactant 2

HCID 21226445Aluminium lithium hydrideHCID 69907597HCID 69907597, compound

Product 1

HCID 69907539HCID 69907539, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

The LiAlH4 reduction of ethyl 3-(4′-cyclohexylphenyl)-but-2-enoate (3b) using THF as solvent under refluxing conditions did not provide the desired compound.

Sources & evidence

ORD record
ord-e58d6675ac75419397d0c60754d8af92
Source dataset
uspto-grants-2004_05
Patent number
US06737438B2

Reaction notes

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