HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethyl Ether → HCID 13533838, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethyl Ether | HCID 3283 | — |
| Reactant | 4-Methylcyclohex-3-en-1-one | HCID 78913 | — |
| Reactant | Sodium borohydride | HCID 4311764 | — |
| Product | HCID 13533838 | HCID 13533838 | — |
Reaction Steps
By procedures similar to those described in Embodiment 3, (+)-2-exo-hydroxy-1-methyl-7-oxabicyclo[2.2.1]heptane was prepared by treatment of 4-methyl-3-cyclohexen-1-one with sodium borohydride followed by epoxidation-cyclization and ether formation to yield the desired product, b.p. 100°-101° C. (0.2 mm).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04554366 |
| Source dataset | uspto-grants-1985_11 |
| ORD ID | ord-6289b423f49b4888935f56bfb5308193 |
| Source note | uspto-grants-1985_11 |