Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
p-Chlorothiophenol → 1-[(4-Chlorophenyl)thio]-1-[(4-methoxyphenyl)hydrazono]-2-propanone
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | p-Chlorothiophenol | HCID 7815 | — |
| 반응물 | Triethylamine | HCID 8471 | — |
| 반응물 | Propanehydrazonoyl chloride, N-(4-methoxyphenyl)-2-oxo- | HCID 2844936 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | 1-[(4-Chlorophenyl)thio]-1-[(4-methoxyphenyl)hydrazono]-2-propanone | HCID 53728696 | — |
반응 단계
A suspension of 31.7 g (0.139 mol) of 1-chloro-1-[(4-methoxyphenyl)hydrazono]-2-propanone in 400 ml of ethanol was treated with 23.4 g (0.161 mole) of 4-chlorothiophenol followed by 23.4 ml of triethylamine. The suspension was heated at reflux for 2 hours and cooled. The resultant suspension was filtered and the precipitate was washed with 1 portion of cold ethanol. The solids were dried in vacuo to yield 1[(4-chlorophenyl)thio]-1-[(4-methoxyphenyl)hydrazono]-2-propanone, mp 111.5-113.5° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05935945 |
| 출처 데이터셋 | uspto-grants-1999_08 |
| ORD ID | ord-d047013e2f51499995df62e4ef90e98c |
| 출처 메모 | uspto-grants-1999_08 |