Allyl Mercaptan → HCID 9859518, compound

HRID 1585986Notes

Reaction equation

HRID 1585986 reaction equation
[Na].[CH2:2]([SH:5])[CH:3]=[CH2:4].Cl[C:7]1[C:16]2[C:11](=[CH:12][CH:13]=[CH:14][CH:15]=2)[C:10]([Cl:17])=[N:9][N:8]=1>CO>[Cl:17][C:10]1[C:11]2[C:16](=[CH:15][CH:14]=[CH:13][CH:12]=2)[C:7]([S:5][CH2:2][CH:3]=[CH2:4])=[N:8][N:9]=1

Participants

5

Reactant 3

HCID 13367Allyl MercaptanHCID 784901,4-DichlorophthalazineHCID 5360545Sodium

Product 1

HCID 9859518HCID 9859518, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

0.23 g(0.01 mol) of metallic sodium was dissolved in 30 ml of absolute methanol and then mixed with 0.93 ml (0.01 mol) of allylmercaptan. To this mixture was added 1.99 g(0.01 mol) of 1,4-dichlorophthalazine. The reaction solution was refluxed for 24 hours and then treated according to the same manner as Example 1 to obtain the title compound as a pale white needle crystal.

Workup

  1. temperatureThe reaction solution was refluxed for 24 hours
  2. additiontreated

Sources & evidence

ORD record
ord-eb55a4b6fdca4492897a07aabff9ae32
Source dataset
uspto-grants-1999_08
Patent number
US05942511

Reaction notes

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