Allyl Mercaptan → HCID 10198535, compound

HRID 1585990Notes

Reaction equation

HRID 1585990 reaction equation
[Na].[CH2:2]([SH:5])[CH:3]=[CH2:4].[CH3:6][O:7][C:8]1[C:17]2[C:12](=[CH:13][CH:14]=[CH:15][CH:16]=2)[C:11](Cl)=[N:10][N:9]=1>CO>[CH3:6][O:7][C:8]1[C:17]2[C:12](=[CH:13][CH:14]=[CH:15][CH:16]=2)[C:11]([S:5][CH2:2][CH:3]=[CH2:4])=[N:10][N:9]=1

Participants

5

Reactant 3

HCID 13367Allyl MercaptanHCID 5360545SodiumHCID 64011971-Chloro-4-methoxy-phthalazine

Product 1

HCID 10198535HCID 10198535, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

0.23 g(0.01 mol) of metallic sodium was dissolved in 30 ml of absolute methanol and then mixed with 0.93 ml(0.01 mol) of allylmercaptan. To this mixture was added 1.95 g(0.01 mol) of 1-methoxy-4-chlorophthalazine obtained from Preparation 7. The reaction solution was refluxed for one hour and then treated according to the same manner as Example 1 to obtain the title compound as a freezing pale white crystal.

Workup

  1. customobtained from Preparation 7
  2. temperatureThe reaction solution was refluxed for one hour
  3. additiontreated

Sources & evidence

ORD record
ord-fed89c9846f7463d81bd519cb371368c
Source dataset
uspto-grants-1999_08
Patent number
US05942511

Reaction notes

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