Allyl Mercaptan → HCID 21217666, compound

HRID 1585991Notes

Reaction equation

HRID 1585991 reaction equation
[Na].[CH2:2]([SH:5])[CH:3]=[CH2:4].[CH2:6]([O:8][C:9]1[N:10]=[N:11][C:12](Cl)=[CH:13][CH:14]=1)[CH3:7]>CO>[CH2:6]([O:8][C:9]1[N:10]=[N:11][CH:12]=[CH:13][C:14]=1[S:5][CH2:2][CH:3]=[CH2:4])[CH3:7]

Participants

5

Reactant 3

HCID 13367Allyl MercaptanHCID 2615793-chloro-6-ethoxypyridazineHCID 5360545Sodium

Product 1

HCID 21217666HCID 21217666, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

0.57 g(0.025 mol) of metallic sodium was dissolved in 40 ml of absolute methanol and then mixed with 2.49 ml(0.025 mol) of allylmercaptan. To this mixture was added 3.96 g(0.025 mol) of 3-ethoxy-6-chloropyridazine. The reaction solution was refluxed for 24 hours and then treated according to the same manner as Example 1 to obtain the title compound as a freezing pale white crystal.

Workup

  1. temperatureThe reaction solution was refluxed for 24 hours
  2. additiontreated

Sources & evidence

ORD record
ord-b78a413db91a4584925d9e7c9d806fe9
Source dataset
uspto-grants-1999_08
Patent number
US05942511

Reaction notes

Loading…