Allyl Mercaptan → HCID 9859359, compound

HRID 1585992Notes

Reaction equation

HRID 1585992 reaction equation
[Na].[CH2:2]([SH:5])[CH:3]=[CH2:4].[CH2:6]([O:8][C:9]1[N:10]=[N:11][C:12](Cl)=[C:13]([CH3:16])[C:14]=1[CH3:15])[CH3:7]>CO>[CH2:6]([O:8][C:9]1[N:10]=[N:11][C:12]([S:5][CH2:2][CH:3]=[CH2:4])=[C:13]([CH3:16])[C:14]=1[CH3:15])[CH3:7]

Participants

5

Reactant 3

HCID 13367Allyl MercaptanHCID 5360545SodiumHCID 21217668HCID 21217668, compound

Product 1

HCID 9859359HCID 9859359, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

0.23 g(0.01 mol) of metallic sodium was dissolved in 100 ml of absolute methanol and then mixed with 0.93 ml(0.01 mol) of allylmercaptan. To this mixture was added 1.87 g(0.01 mol) of 3-ethoxy-4,5-dimethyl-6-chloropyridazine obtained from Preparation 8. The reaction solution was refluxed for 3 hours and then treated according to the same manner as Example 1 to obtain the title compound as a freezing white crystal.

Workup

  1. customobtained from Preparation 8
  2. temperatureThe reaction solution was refluxed for 3 hours
  3. additiontreated

Sources & evidence

ORD record
ord-9f02ee0cc0114938816de1c753d67bff
Source dataset
uspto-grants-1999_08
Patent number
US05942511

Reaction notes

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