Allyl Mercaptan → HCID 9794857, compound

HRID 1585994Notes

Reaction equation

HRID 1585994 reaction equation
[Na].[CH2:2]([SH:5])[CH:3]=[CH2:4].[CH2:6]([O:8][C:9]1[C:18]2[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=2)[C:12](Cl)=[N:11][N:10]=1)[CH3:7]>CO>[CH2:6]([O:8][C:9]1[C:18]2[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=2)[C:12]([S:5][CH2:2][CH:3]=[CH2:4])=[N:11][N:10]=1)[CH3:7]

Participants

5

Reactant 3

HCID 13367Allyl MercaptanHCID 5360545SodiumHCID 212176601-Chloro-4-ethoxyphthalazine

Product 1

HCID 9794857HCID 9794857, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

0.23 g(0.01 mol) of metallic sodium was dissolved in 100 ml of absolute methanol and then mixed with 0.93 ml(0.01 mol) of allylmercaptan. To this mixture was added 2.09 g(0.01 mol) of 1-ethoxy-4-chlorophthalazine obtained from Preparation 10. The reaction solution was refluxed for 3 hours and then treated according to the same manner as Example 1 to obtain the title compound as a freezing white crystal.

Workup

  1. customobtained from Preparation 10
  2. temperatureThe reaction solution was refluxed for 3 hours
  3. additiontreated

Sources & evidence

ORD record
ord-410766fcd3fc46009dbb63f29386785c
Source dataset
uspto-grants-1999_08
Patent number
US05942511

Reaction notes

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