Allyl Mercaptan → HCID 21217655, compound

HRID 1586000Notes

Reaction equation

HRID 1586000 reaction equation
[Na].[CH2:2]([SH:5])[CH:3]=[CH2:4].[CH2:6]([O:11][C:12]1[N:13]=[N:14][C:15](Cl)=[CH:16][CH:17]=1)[CH2:7][CH2:8][CH2:9][CH3:10]>CO>[CH2:6]([O:11][C:12]1[N:13]=[N:14][C:15]([S:5][CH2:2][CH:3]=[CH2:4])=[CH:16][CH:17]=1)[CH2:7][CH2:8][CH2:9][CH3:10]

Participants

5

Reactant 3

HCID 13367Allyl MercaptanHCID 5360545SodiumHCID 12285836Pyridazine, 3-chloro-6-(pentyloxy)-

Product 1

HCID 21217655HCID 21217655, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

1.15 g(0.05 mol) of metallic sodium was dissolved in 75 ml of absolute methanol and then mixed with 4.98 ml(0.05 mol) of allylmercaptan. To this mixture was added 10.03 g(0.05 mol) of 3-(n-pentyloxy)-6-chloropyridazine. The reaction solution was refluxed for 24 hours and then treated according to the same manner as Example 1 to obtain the title compound as a pale yellow needle crystal.

Workup

  1. temperatureThe reaction solution was refluxed for 24 hours
  2. additiontreated

Sources & evidence

ORD record
ord-74517d8125aa41d19c5f27b7177fe424
Source dataset
uspto-grants-1999_08
Patent number
US05942511

Reaction notes

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