Allyl Mercaptan → HCID 21217670, compound

HRID 1586001Notes

Reaction equation

HRID 1586001 reaction equation
[Na].[CH2:2]([SH:5])[CH:3]=[CH2:4].[CH2:6]([O:11][C:12]1[N:13]=[N:14][C:15](Cl)=[CH:16][CH:17]=1)[CH2:7][CH:8]([CH3:10])[CH3:9]>CO>[CH2:6]([O:11][C:12]1[N:13]=[N:14][C:15]([S:5][CH2:2][CH:3]=[CH2:4])=[CH:16][CH:17]=1)[CH2:7][CH:8]([CH3:10])[CH3:9]

Participants

5

Reactant 3

HCID 13367Allyl MercaptanHCID 2528263-Chloro-6-(3-methylbutoxy)pyridazineHCID 5360545Sodium

Product 1

HCID 21217670HCID 21217670, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

1.15 g(0.05 mol) of metallic sodium was dissolved in 150 ml of absolute methanol and then mixed with 4.98 ml(0.05 mol) of allylmercaptan. To this mixture was added 10.03 g(0.05 mol) of 3-isopentyloxy-6-chloropyridazine. The reaction solution was refluxed for 24 hours and then treated according to the same manner as Example 1 to obtain the title compound as a pale yellow oil.

Workup

  1. temperatureThe reaction solution was refluxed for 24 hours
  2. additiontreated

Sources & evidence

ORD record
ord-05db89f258dd44e4a3c0f0f4bce562e8
Source dataset
uspto-grants-1999_08
Patent number
US05942511

Reaction notes

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