Allyl Mercaptan → HCID 10219981, compound

HRID 1586002Notes

Reaction equation

HRID 1586002 reaction equation
[Na].[CH2:2]([SH:5])[CH:3]=[CH2:4].[OH:6][CH2:7][CH2:8][O:9][C:10]1[N:11]=[N:12][C:13](Cl)=[CH:14][CH:15]=1>CO>[OH:6][CH2:7][CH2:8][O:9][C:10]1[N:11]=[N:12][C:13]([S:5][CH2:2][CH:3]=[CH2:4])=[CH:14][CH:15]=1

Participants

5

Reactant 3

HCID 13367Allyl MercaptanHCID 5360545SodiumHCID 14343567122913-80-8

Product 1

HCID 10219981HCID 10219981, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

0.23 g(0.01 mol) of metallic sodium was dissolved in 30 ml of absolute methanol and then mixed with 1.00 ml(0.01 mol) of allylmercaptan. To this mixture was added 1.75 g(0.01 mol) of 3-(2-hydroxyethoxy)-6-chloropyridazine. The reaction solution was refluxed for 24 hours and then treated according to the same manner as Example 1 to obtain the title compound as a pale white needle crystal.

Workup

  1. temperatureThe reaction solution was refluxed for 24 hours
  2. additiontreated

Sources & evidence

ORD record
ord-fd34e192f5ca401d8e966cabc950c911
Source dataset
uspto-grants-1999_08
Patent number
US05942511

Reaction notes

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