Sodium Carbonate → HCID 135532380, compound

HRID 1586210Notes

Reaction equation

HRID 1586210 reaction equation
[OH:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8]1[N:13]=[C:12]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][C:15]=2[OH:20])[N:11]=[C:10]([C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)[N:9]=1.P(=O)(O)O.[CH3:31]CC.C(=O)([O-])[O-].[Na+].[Na+]>C(O)C>[CH3:31][O:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8]1[N:13]=[C:12]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][C:15]=2[OH:20])[N:11]=[C:10]([C:21]2[CH:22]=[CH:23][CH:24]=[CH:25][CH:26]=2)[N:9]=1

Participants

5

Reactant 3

HCID 10340Sodium CarbonateHCID 135810727HCID 135810727, compoundHCID 178460562HCID 178460562, compound

Product 1

HCID 135532380HCID 135532380, compoundYield 94.5%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Conditions

Temperature
150 °C

Procedure

9.6 g (0.028 mol) of 2,4-bis(2'-hydroxyphenyl)-6-phenyl-s-triazine, 25 ml (0.234 mol) of dimethylmethane phosphonate and 4.0 g (0.028 mol) of sodium carbonate are mixed and the mixture is heated to 150° C. After 2 hours the clear, pale red reaction solution is stirred into 150 ml of ethanol. The precipitate is filtered with suction, rinsed with 20 ml of ethanol and water and dried in an exsiccator, giving 9.4 g (94.1%) of the compound of formula ##STR7##

Workup

  1. filtrationThe precipitate is filtered with suction
  2. washrinsed with 20 ml of ethanol and water
  3. customdried in an exsiccator

Sources & evidence

ORD record
ord-67736a1518d24656bfd4276a1adab918
Source dataset
uspto-grants-1999_08
Patent number
US05942564

Reaction notes

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