N,N,N',N'-Tetramethylazodicarboxamide → HCID 19760453, compound

HRID 1587041Notes

Reaction equation

HRID 1587041 reaction equation

[N+](C1C=CC=CC=1)([O-])=O.C[N:11]([C:13]([N:15]=NC(N(C)C)=O)=O)C.[C:22]1([N:28]2[C:32](=[O:33])[CH2:31][CH2:30][C:29]2=[O:34])[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1>>[C:13]([NH:15][C:32](=[O:33])[CH2:31][CH2:30][C:29]([NH:28][C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1)=[O:34])#[N:11]

Participants

4

Reactant 3

HCID 4278N,N,N',N'-Tetramethylazodicarboxamide

HCID 7416Nitrobenzene

HCID 66519Succinanil

Product 1

HCID 19760453HCID 19760453, compound

Procedure

Using high temperature NMR techniques (150° C., nitrobenzene), the rapid conversion of the diamide to N-phenylsuccinimide was observed.

Sources & evidence

ORD record: ord-05775b4f326b4f59bc167f200ec27919
Source dataset: uspto-grants-1993_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05216173

Reaction notes

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