Nitroethane → HCID 54097466, compound

HRID 1587046Notes

Reaction equation

HRID 1587046 reaction equation
[CH2:1]([O:3][CH2:4][CH2:5][O:6][C:7]1[CH:12]=[CH:11][C:10]([CH:13]=O)=[CH:9][N:8]=1)[CH3:2].[N+:15]([CH2:18][CH3:19])([O-:17])=[O:16].C([O-])(=O)C.[NH4+]>C(O)(=O)C.O>[CH2:1]([O:3][CH2:4][CH2:5][O:6][C:7]1[CH:12]=[CH:11][C:10]([CH:13]=[C:18]([N+:15]([O-:17])=[O:16])[CH3:19])=[CH:9][N:8]=1)[CH3:2]

Participants

6

Reactant 3

HCID 6587NitroethaneHCID 517165Ammonium AcetateHCID 15067079HCID 15067079, compound

Product 1

HCID 54097466HCID 54097466, compound

Reagents, catalysts & solvents 2

HCID 176Acetic AcidSolventHCID 962WaterSolvent

Procedure

A mixture of 8.3 g (42.6 mmol) of 2-(2-ethoxyethoxy)-pyridine-5-aldehyde, 5.53 g, (73.7 mmol) of nitroethane and 3.83 g (49.7 mmol) of ammonium acetate in 50 ml of glacial acetic acid is heated under reflux for 7 hours. The mixture is then diluted with water while cooling in ice, and the product is filtered off with suction.

Workup

  1. temperatureis heated
  2. temperatureunder reflux for 7 hours
  3. temperaturewhile cooling in ice
  4. filtrationthe product is filtered off with suction

Sources & evidence

ORD record
ord-c1fb0774bcfe408d931b24205163cee3
Source dataset
uspto-grants-1993_06
Patent number
US05216170

Reaction notes

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