HCID 19757916, compound → HCID 19757886, compound

HRID 1587541Notes

Reaction equation

HRID 1587541 reaction equation
[SH:1][C:2]1[CH:7]=[CH:6][C:5]([CH2:8][N:9](C(OC(C)(C)C)=O)[CH2:10][CH2:11][CH2:12][CH2:13][N:14](C(OC(C)(C)C)=O)[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][N:22](C(OC(C)(C)C)=O)[CH2:23][CH2:24][CH2:25][CH2:26][N:27]([CH2:35][C:36]2[CH:41]=[CH:40][C:39]([SH:42])=[CH:38][CH:37]=2)C(OC(C)(C)C)=O)=[CH:4][CH:3]=1>Cl>[SH:1][C:2]1[CH:3]=[CH:4][C:5]([CH2:8][NH:9][CH2:10][CH2:11][CH2:12][CH2:13][NH:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][NH:22][CH2:23][CH2:24][CH2:25][CH2:26][NH:27][CH2:35][C:36]2[CH:37]=[CH:38][C:39]([SH:42])=[CH:40][CH:41]=2)=[CH:6][CH:7]=1

Participants

3

Reactant 1

HCID 19757916HCID 19757916, compound

Product 1

HCID 19757886HCID 19757886, compound

Reagents, catalysts & solvents 1

HCID 313Hydrochloric AcidSolvent

Procedure

Dissolve 1,19-bis[(4-mercaptophenyl)methyl]-1,6,14,19-tetra(t-butyloxycarbonyl)-1,6,14,19-tetraazanonadecane (9.60 g, 10 mmol) in saturated methanolic hydrochloric acid (100 mL). Stir for several hours and evaporate the solvent in vacuo to give the title compound.

Workup

  1. customevaporate the solvent in vacuo

Sources & evidence

ORD record
ord-081fab0fa6714de380f967d02721bfaf
Source dataset
uspto-grants-1993_06
Patent number
US05217964

Reaction notes

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