1,3-Dimethyl-2-imidazolidinone → HCID 136331488, compound

HRID 1587746Notes

Reaction equation

HRID 1587746 reaction equation
C(O[CH:4](OCC)[N:5]1[CH2:9][CH2:8][NH:7][C:6]1=[N:10][N+:11]([O-:13])=[O:12])C.[SH:17][C:18]1[CH:24]=[CH:23][CH:22]=[CH:21][C:19]=1[NH2:20].[CH3:25]N1CCN(C)C1=O>C(OCC)(=O)C>[CH3:25][S:17][C:18]1[CH:24]=[CH:23][CH:22]=[CH:21][C:19]=1[N:20]=[CH:4][N:5]1[CH2:9][CH2:8][NH:7][C:6]1=[N:10][N+:11]([O-:13])=[O:12]

Participants

5

Reactant 3

HCID 66611,3-Dimethyl-2-imidazolidinoneHCID 87132-AminothiophenolHCID 1364034191-Diethoxymethyl-2-nitroiminoimidazolidine

Product 1

HCID 136331488HCID 136331488, compound

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

0.05 g of boron trifluoride ether complex was added to a mixture of 46.4 g of 1-diethoxymethyl-2-nitroiminoimidazolidine, 27.8 g of 2-mercaptoaniline and 120 ml of 1.3-dimethyl-2-imidazolidinone under ice-cooling conditions, followed by agitation for 20 minutes. About 200 ml of ethyl acetate was added to the reaction mixture, and the resultant crystals were collected by filtration, washed with hexane and dried to give 61 g of 1-(2-methylmercaptophenyliminomethyl)-2-nitroiminoimidazolidine.

Workup

  1. temperaturecooling conditions
  2. filtrationthe resultant crystals were collected by filtration
  3. washwashed with hexane
  4. customdried

Sources & evidence

ORD record
ord-14c9c79a24444c63a34054818c04eb48
Source dataset
uspto-grants-1993_06
Patent number
US05219868

Reaction notes

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