huagongshe.com
HRID1588050

反应详情

EQUATION

反应方程式

HRID 1588050 的结构方程式

REACTANTS

反应物

2
结构：[N-]=[N+]=CC(=O)c1ccccc1
HCID18667

未命名化合物

结构：C=C(P(=O)(OCC)OCC)P(=O)(OCC)OCC
HCID11022954

Tetraethyl vinylidene phosphonate

C10H22O6P2

PRODUCTS

生成物

1
结构：CCOP(=O)(OCC)C1(P(=O)(OCC)OCC)CC(C(=O)c2ccccc2)=NN1
HCID3076818

Phosphonic acid, (5-benzoyl-2,4-dihydro-3H-pyrazol-3-ylidene)bis-, tetraethyl ester

C18H28N2O7P2

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCOCC
溶剂HCID3283

Diethyl Ether

C4H10O

PROCEDURE

实验过程

Ethenylidene bisphosphonic acid tetraethyl ester (II, PREPARATION 1, 6.00 g) in ether (20 ml) is treated with solid 2-diazo-1-phenylethanone (2.92 g) and stirred at 22° for 20 hrs. The precipitate is collected and washed with ether to give the title compound. An analytical sample is obtained by recrystallization from methylene chloride/hexane, mp 133.5°-134°; MS (m/e) 446, 327, 309, 281, 271, 253, 243, 215, 175; IR (mineral oil mull) 3183, 1631, 1600, 1578, 1548, 1433, 1260, 1242, 1161, 1067, 1043, 1020, 1001, 995, 976 and 962 cm-1 ; NMR (CDCl3) 8.10, 7.50, 6.90, 4.27, 3.69 and 1.34 δ.

WORKUP

后处理

  1. customThe precipitate is collected
  2. washwashed with ether