참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Ethylene carbonate | HCID 7303 | — |
| 반응물 | p-Isopropenylphenol | HCID 584247 | — |
| 반응물 | Potassium fluoride dihydrate | HCID 23708904 | — |
| 용매 | Dimethylformamide | HCID 6228 | — |
| 생성물 | 2-(4-(1-Methylethenyl)phenoxy)ethanol | HCID 13750613 | 69% |
반응 단계
A mixture of 20 g p-isopropenylphenol, 1.1 equivalents ethylene carbonate, 0.02 equivalent potassium fluoride dihydrate, and 200 ml N,N-dimethylformamide (DMF) was heated at about 150° C. for about 1.5 hours. After removal of DMF under reduced pressure, the crude product was distilled. 2-(4-(1-Methylethenyl)phenoxy)ethanol, bp 143° C./7 torr, was obtained as a white solid in 69% yield.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04568497 |
|---|
| 출처 데이터셋 | uspto-grants-1986_02 |
|---|
| ORD ID | ord-1f0c4176d92445d0a3f1eda6fed5ce78 |
|---|
| 출처 메모 | uspto-grants-1986_02 |
|---|
