N,N-Dimethylethylenediamine → HCID 10867066, compound

HRID 1589203Notes

Reaction equation

HRID 1589203 reaction equation
[C:1]([N:3]=[C:4](SC)[S:5][CH3:6])#[N:2].[CH3:9][N:10]([CH3:14])[CH2:11][CH2:12][NH2:13]>C(O)C>[C:1]([NH:3][C:4](=[N:13][CH2:12][CH2:11][N:10]([CH3:14])[CH3:9])[S:5][CH3:6])#[N:2]

Participants

4

Reactant 2

HCID 66053N,N-DimethylethylenediamineHCID 66289Dimethyl N-cyanodithioiminocarbonate

Product 1

HCID 10867066HCID 10867066, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A stirred solution of N-cyano-bis(methylthio)methanimine (30 g) in warm ethanol (150 ml) was treated dropwise with 2-dimethylaminoethylamine (24 ml) during 1 hour and stirring was continued for a further period of 3 hours. The resulting white precipitate was recrystallised from ethanol, to give N-cyano-N'-(2-dimethylaminoethyl)-S-methylisothiourea (13.4 g), m.p. 94°-95° C.

Workup

  1. customThe resulting white precipitate was recrystallised from ethanol

Sources & evidence

ORD record
ord-95ef3f907f47434ca33edd73d8ec9b13
Source dataset
uspto-grants-1986_02
Patent number
US04568694

Reaction notes

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