Hydrochloric Acid → HCID 136387260, compound

HRID 1589490Notes

Reaction equation

HRID 1589490 reaction equation
[Cl:1][C:2]1[CH:7]=[C:6]([C:8]#[N:9])[CH:5]=[CH:4][C:3]=1[OH:10].Cl.[CH2:12]([O:14]CC)C>CO>[ClH:1].[Cl:1][C:2]1[CH:7]=[C:6]([CH:8]=[N:9][O:14][CH3:12])[CH:5]=[CH:4][C:3]=1[OH:10]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 3283Diethyl EtherHCID 2735739Benzonitrile, 3-chloro-4-hydroxy-

Product 1

HCID 136387260HCID 136387260, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

While being cooled in ice, a solution of 4.5 g of 2-chloro-4-cyanophenol in 50 ml of methanol was saturated with dried gaseous hydrogen chloride (HCl). The solution was left standing overnight at room temperature and mixed with 100 ml of ethyl ether to precipitate crystals which were collected by filtration to obtain 4.0 g of 2-chloro-4-methoxyiminomethylphenol hydrochloride.

Workup

  1. temperatureWhile being cooled in ice
  2. waitThe solution was left
  3. customto precipitate crystals which
  4. filtrationwere collected by filtration

Sources & evidence

ORD record
ord-1f9198b9f1d04f869c7b9fe59c41080d
Source dataset
uspto-grants-1986_02
Patent number
US04570006

Reaction notes

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