Methyldidecylsilyl-1-decene → Methyltridecylsilane

HRID 1589607Notes

Reaction equation

HRID 1589607 reaction equation
CC([SiH:12]([CH2:23]CCCCCCCCC)[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])=CCCCCCCCC.[CH3:33][CH:34]([SiH](CCCCCCCCCC)CCCCCCCCCC)[CH:35]=CCCCCCCC>C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.[Cl-].[Rh]>[CH3:23][SiH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:33][CH2:34][CH3:35]

Participants

4

Reactant 2

HCID 131714527Methyldidecylsilyl-1-deceneHCID 131714528Methyldidecylsilyl-2-decene

Product 1

HCID 123907608MethyltridecylsilaneYield 85%

Reagents, catalysts & solvents 1

HCID 84599Chlorotris(triphenylphosphine)rhodium(I)Catalyst

Procedure

The test of Example 20 was repeated using 0.005 gram of chlorotris(triphenylphosphine)rhodium(I). The reaction was over in one hour at 50° C., and produced an 85 percent yield of methyltridecylsilane and 15 percent of methyldidecylsilyl-1-decene and methyldidecylsilyl-2-decene.

Workup

  1. customwas over in one hour at 50° C.

Sources & evidence

ORD record
ord-05f2a86b151c44cfa99c4f4b6a0f3da7
Source dataset
uspto-grants-1986_02
Patent number
US04572791

Reaction notes

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