HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyldidecylsilyl-1-decene → Methyltridecylsilane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyldidecylsilyl-1-decene | HCID 131714527 | — |
| Reactant | Methyldidecylsilyl-2-decene | HCID 131714528 | — |
| Catalyst | Chlorotris(triphenylphosphine)rhodium(I) | HCID 84599 | — |
| Product | Methyltridecylsilane | HCID 123907608 | 85% |
Reaction Steps
The test of Example 20 was repeated using 0.005 gram of chlorotris(triphenylphosphine)rhodium(I). The reaction was over in one hour at 50° C., and produced an 85 percent yield of methyltridecylsilane and 15 percent of methyldidecylsilyl-1-decene and methyldidecylsilyl-2-decene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04572791 |
| Source dataset | uspto-grants-1986_02 |
| ORD ID | ord-05f2a86b151c44cfa99c4f4b6a0f3da7 |
| Source note | uspto-grants-1986_02 |