Potassium Carbonate → Undecane

HRID 1590143Notes

Reaction equation

HRID 1590143 reaction equation
N12CS[CH2:9][CH:8]1[CH2:7][CH:6]1[CH:2]2[CH2:3]N(C(OCC)=O)C1.C(=O)([O-])[O-].[K+].[K+]>O>[CH3:3][CH2:2][CH2:6][CH2:7][CH2:8][CH2:9][CH2:8][CH2:7][CH2:6][CH2:2][CH3:3]

Participants

4

Reactant 2

HCID 11430Potassium CarbonateHCID 54120114HCID 54120114, compound

Product 1

HCID 14257Undecane

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

12.5 g (50 mmol) of ethyl 10-thia-1,4-diazatricyclo[6.3.0.02,6 ]undecane-4-carboxylate together with 32 g of Ba(OH)2 ×8H2O are refluxed overnight in 225 ml of water. Potassium carbonate is added, barium carbonate is filtered off with suction, and the filtrate is extracted ten times using 100 ml portions of chloroform. The extracts are dried over potassium carbonate, concentrated and distilled.

Workup

  1. filtrationbarium carbonate is filtered off with suction
  2. extractionthe filtrate is extracted ten times
  3. dry with materialThe extracts are dried over potassium carbonate
  4. concentrationconcentrated
  5. distillationdistilled

Sources & evidence

ORD record
ord-050b7de1cffe4896a9a84329fe3d034b
Source dataset
uspto-grants-1993_04
Patent number
US05202337

Reaction notes

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