2-Bromobiphenyl → 4'-Methyl-2-phenyl-1,1'-biphenyl

HRID 1591490Notes

Reaction equation

HRID 1591490 reaction equation
Br[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1.[CH3:14][C:15]1[CH:20]=[CH:19][C:18]([Sn](C)(C)C)=[CH:17][CH:16]=1>>[CH3:14][C:15]1[CH:20]=[CH:19][C:18]([C:13]2[CH:12]=[CH:11][CH:10]=[CH:9][C:8]=2[C:3]2[CH:2]=[CH:7][CH:6]=[CH:5][CH:4]=2)=[CH:17][CH:16]=1

Participants

3

Reactant 2

HCID 163292-BromobiphenylHCID 617834Stannane, trimethyl(4-methylphenyl)-

Product 1

HCID 185101174'-Methyl-2-phenyl-1,1'-biphenyl

Procedure

Prepared from 2-bromobiphenyl and 4-methylphenyltrimethylstannane by the procedure described in Example 69, Step B.

Sources & evidence

ORD record
ord-6ce4062b244f49afbfb8701385621d35
Source dataset
uspto-grants-1993_04
Patent number
US05206235

Reaction notes

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