Ethyl [1-(diphenylmethyl)azetidin-3-ylidene]acetate → HCID 54328202, compound

HRID 1596182Notes

Reaction equation

HRID 1596182 reaction equation
[CH2:1]([O:3][C:4](=[O:23])[CH:5]=[C:6]1[CH2:9][N:8](C(C2C=CC=CC=2)C2C=CC=CC=2)[CH2:7]1)[CH3:2].[H][H]>C(O)C.[OH-].[OH-].[Pd+2]>[CH2:1]([O:3][C:4](=[O:23])[CH2:5][CH:6]1[CH2:9][NH:8][CH2:7]1)[CH3:2]

Participants

5

Reactant 2

HCID 53428664Ethyl [1-(diphenylmethyl)azetidin-3-ylidene]acetateHCID 178418361HCID 178418361, compound

Product 1

HCID 54328202HCID 54328202, compound

Reagents, catalysts & solvents 2

HCID 9942167Palladium hydroxideCatalystHCID 702EthanolSolvent

Procedure

To a solution of (1-benzhydrylazetidin-3-ylidene)-acetic acid ethyl ester (5.0 g, 16 mmol) in ethanol (200 mL) was added palladium hydroxide on carbon (1.5 g). This mixture was vigorously shaken under a 50 psi hydrogen atmosphere for 24 hrs, then filtered and concentrated to give an oil, used without additional purification.

Workup

  1. filtrationfiltered
  2. concentrationconcentrated
  3. customto give an oil
  4. customused without additional purification

Sources & evidence

ORD record
ord-0d8c71ddcce741c880b4bf11130e10cc
Source dataset
uspto-grants-2001_09
Patent number
US06291457B1

Reaction notes

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