Methanol → HCID 178524314, compound
Reaction equation
[OH-:1].[Ca+2:2].[OH-:3].[B:4]([OH:7])([OH:6])[OH:5].[C:8]1([CH3:15])[C:9](C)=[CH:10][CH:11]=[CH:12][CH:13]=1.C[OH:17]>O>[B:4]([O-:7])([O-:6])[O-:5].[Ca+2:2].[B:4]([O-:7])([O-:6])[O-:5].[Ca+2:2].[Ca+2:2].[C:15]([O-:17])(=[O:3])[C:8]1[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=1)[OH:1]Participants
Reactant 4
Product 1
Reagents, catalysts & solvents 1
Conditions
- Temperature
- 40 °C
Procedure
A solution of 100 parts by weight of a neutral calcium alkyl-salicylate in 100 parts by weight of a lubricating oil fraction, 24 parts by weight of calcium hydroxide, 40 parts by weight (2.0 moles per mole of the calcium hydroxide) of orthoboric acid and 400 parts by weight of xylene were put in a 1000-ml four-necked flask fitted with a condenser and heated to 40° C. under agitation. To this mixture were added 60 parts by weight of methanol and 10 parts by weight of water and the resulting mixture was heated under agitation to the reflux temperature (60° C.) and reacted for 3 hours. The reaction mixture was further heated to 140° C. to distil out the methanol, water and xylene. Finally the reaction product was diluted twofold with hexane and filtered, and the hexane was distilled out to leave the desired calcium borate overbased alkyl-salicylate (calcium borate-salicylate).
Workup
- customfitted with a condenser
- temperaturethe resulting mixture was heated under agitation to the reflux temperature (60° C.)
- customreacted for 3 hours
- temperatureThe reaction mixture was further heated to 140° C.
- customto distil out the methanol, water and xylene
- additionFinally the reaction product was diluted twofold with hexane
- filtrationfiltered
- distillationthe hexane was distilled out
Sources & evidence
- ORD record
- ord-a990e0b51826417abd2b9fdae49cdd5b
- Source dataset
- uspto-grants-1998_04
- Patent number
- US05739088
Reaction notes
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