Water → Vinylidene fluoride

HRID 1598922Notes

Reaction equation

HRID 1598922 reaction equation
[OH2:1].[C:2]([F:5])([F:4])=[CH2:3].[C:6]([O:13][CH3:14])(=[O:12])/[CH:7]=[CH:8]\[C:9]([O-:11])=[O:10]>C(OCC)(=O)C>[C:6]([O:12][O:13][C:6]([O:12][CH:2]([CH3:3])[CH3:3])=[O:1])([O:13][CH:14]([CH3:2])[CH3:14])=[O:1].[C:2]([F:5])([F:4])=[CH2:3].[C:6]([O:13][CH3:14])(=[O:12])/[CH:7]=[CH:8]\[C:9]([O-:11])=[O:10]

Participants

6

Reactant 2

HCID 962WaterHCID 86752396HCID 86752396, compound

Product 3

HCID 6369Vinylidene fluorideHCID 7769Diisopropyl peroxydicarbonateHCID 21768182Mono-methyl maleate

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

Into a 2 liter-autoclave, 1000 g of deionized water, 0.8 g of methylcellulose, 2.5 g of ethyl acetate, 4 g of di-iso-propyl peroxydicarbonate (IPP), 396 g of vinylidene fluoride, and 4 g of monomethyl maleate (giving a vinylidene fluoride/monomethyl maleate (mol ratio)=100/0.50), were charged and subjected to suspension polymerization at 28° C. for 47 hours.

Sources & evidence

ORD record
ord-45a44aae5d8f495ebfb351f7ebd426f8
Source dataset
uspto-grants-1998_04
Patent number
US05739234

Reaction notes

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