Sulfuryl chloride → HCID 15672345, compound

HRID 1599984Notes

Reaction equation

HRID 1599984 reaction equation
[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[C:5]([CH3:9])=[CH:4][C:3]=1[C:10]1[CH:14]=[C:13]([O:15][CH:16]([F:18])[F:17])[N:12]([CH3:19])[N:11]=1.S(Cl)([Cl:23])(=O)=O>>[Cl:23][C:14]1[C:10]([C:3]2[CH:4]=[C:5]([CH3:9])[C:6]([Cl:8])=[CH:7][C:2]=2[Cl:1])=[N:11][N:12]([CH3:19])[C:13]=1[O:15][CH:16]([F:17])[F:18]

Participants

3

Reactant 2

HCID 24648Sulfuryl chlorideHCID 15672343HCID 15672343, compound

Product 1

HCID 15672345HCID 15672345, compound

Procedure

Analogously to Example 8, 35 g (114 mmol) of 3-(2,4-dichloro-5-methylphenyl)-5-difluoromethoxy-1-methyl-1H-pyrazole were reacted with 16.9 g (125 mmol) of sulfuryl chloride. Yield: 30.8 g; 1H-NMR (270 MHz, in CDCl3): δ [ppm]=7.49 (s,1H), 7.30 (s,1H), 6.74 (t,1H), 3.85 (s,3H), 2.39 (s,3H).

Sources & evidence

ORD record
ord-5f7cb530ec94455692977c5284e8b4f1
Source dataset
uspto-grants-1998_04
Patent number
US05744426

Reaction notes

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