Acetylacetone → Cerium nitrate

HRID 1600490Notes

Reaction equation

HRID 1600490 reaction equation
C(CC(=O)C)(=O)C.O.O.O.O.O.O.[N+:14]([O-:17])([O-:16])=[O:15].[Ce+3:18].[N+:19]([O-:22])([O-:21])=[O:20].[N+:23]([O-:26])([O-:25])=[O:24]>>[N+:14]([O-:17])([O-:16])=[O:15].[Ce+3:18].[N+:19]([O-:22])([O-:21])=[O:20].[N+:23]([O-:26])([O-:25])=[O:24]

Participants

3

Reactant 2

HCID 31261AcetylacetoneHCID 16211466Cerous nitrate hexahydrate

Product 1

HCID 24948Cerium nitrate

Conditions

Temperature
90 °C

Procedure

3 moles of acetylacetone was added to 1 mole of cerium nitrate hexahydrate and heated to 90° C. under agitation under which the mixture was treated for 1 hour. The solution was provided as cerium nitrate stock solution. This had a CeO2 solid content of 23.2%.

Workup

  1. additionwas treated for 1 hour

Sources & evidence

ORD record
ord-8ed2e921bb1241bcb783c5c758d97255
Source dataset
uspto-grants-1999_11
Patent number
US05976678

Reaction notes

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