Sodium Hydroxide → HCID 18466815, compound

HRID 1601004Notes

Reaction equation

HRID 1601004 reaction equation
[CH3:1][C:2]1([CH3:19])[CH2:15][CH2:14][C:13]([CH3:17])([CH3:16])[C:12]2[N:11]=[C:10]3[C:5]([CH2:6][CH2:7][CH2:8][C:9]3=[O:18])=[N:4][C:3]1=2.[CH3:20][O:21][C:22]([C:24]1[CH:29]=[CH:28][C:27]([CH:30]=[O:31])=[CH:26][CH:25]=1)=[O:23].[OH-].[Na+]>CO>[CH3:1][C:2]1([CH3:19])[CH2:15][CH2:14][C:13]([CH3:17])([CH3:16])[C:12]2[N:11]=[C:10]3[C:5]([CH2:6][CH2:7][CH:8]([CH:30]([OH:31])[C:27]4[CH:26]=[CH:25][C:24]([C:22]([O:21][CH3:20])=[O:23])=[CH:29][CH:28]=4)[C:9]3=[O:18])=[N:4][C:3]1=2

Participants

5

Reactant 3

HCID 14798Sodium HydroxideHCID 15294Methyl 4-FormylbenzoateHCID 18466674HCID 18466674, compound

Product 1

HCID 18466815HCID 18466815, compoundYield 64.8%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

0.5 g of 1,2,3,4,6,7,8,9-octahydro-6,6,9,9-tetramethylphenazin-1-one and 0.38 g of methyl terephthalaldehydate were dissolved in 15 ml of methanol, followed by the addition of a small amount of sodium hydroxide. The obtained mixture was stirred overnight to precipitate crystals. The crystals were recovered by filtration, washed with a small amount of methanol and dried in a vacuum to give 0.53 g of the title compound as a white solid.

Workup

  1. customto precipitate crystals
  2. filtrationThe crystals were recovered by filtration
  3. washwashed with a small amount of methanol
  4. customdried in a vacuum

Sources & evidence

ORD record
ord-5b50651bad5b4c00a3d7e1aad286d32e
Source dataset
uspto-grants-1999_11
Patent number
US05977125

Reaction notes

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