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HRID1602199

反应详情

EQUATION

反应方程式

HRID 1602199 的结构方程式

REACTANTS

反应物

2
结构：COc1cc(C=O)c([N+](=O)[O-])cc1OC
HCID88505

6-Nitroveratraldehyde

C9H9NO5

结构：COc1ccc2c(c1OC)CCC(=O)C2
HCID4610752

5,6-dimethoxy-3,4-dihydro-1H-naphthalen-2-one

C12H14O3

PRODUCTS

生成物

1
结构：COc1cc(C=C2C(=O)CCc3c2ccc(OC)c3OC)c([N+](=O)[O-])cc1OC
HCID53763953

未命名化合物

PROCEDURE

实验过程

Prepared from 5,6-dimethoxy-2-tetralone and 2-nitro-4,5-dimethoxybenzaldehyde; mp 70-72° C.; IR (Nujol): 1715, 1550; 1H NMR: δ2.59 (2H, t), 3.06 (2H, t), 3.78 (3H, s), 3.86 (3H, s), 3.88 (3H, s), 3.92 (3H, s), 6.47 (1H, s), 6.77 (1H, d, J=8.2), 7.41 (1H, d, J=8.2), 7.67 (1H, s); 13C NMR: δ19.7, 32.0, 56.3, 56.7, 56.8, 56.85, 108.1, 121.9, 125.6, 126.1, 128.0, 129.2, 132.1, 132.9, 133.7, 140.3, 141.4, 149.3, 152.9, 153.5, 200.9; Anal. (C21H21NO7) C, H, N.