Potassium Formate → HCID 19611269, compound

HRID 1602359Notes

Reaction equation

HRID 1602359 reaction equation
Br[CH2:2][C:3]1[O:4][C:5](=[O:10])[O:6][C:7]=1[CH2:8][Br:9].[CH:11]([O-:13])=[O:12].[K+]>C(#N)C>[Br:9][CH2:8][C:7]1[O:6][C:5](=[O:10])[O:4][C:3]=1[CH2:2][O:13][CH:11]=[O:12]

Participants

4

Reactant 2

HCID 2735122Potassium FormateHCID 123258494,5-Bis(bromomethyl)-2H-1,3-dioxol-2-one

Product 1

HCID 19611269HCID 19611269, compoundYield 65%

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Conditions

Temperature
25 °C

Procedure

4,5-Dibromomethyl-2-oxo-1,3-dioxolene (150 mg, 0.55 mmol) was dissolved in acetonitrile (4.0 mL). Potassium formate (46 mg, 0.55 mmol) was added thereto. This mixture was stirred at 25° C. for 5 hours. Through the ordinary post-treatment, crude Compound S-30 (85 mg, yield 65%) was obtained.

Workup

  1. custom(85 mg, yield 65%) was obtained

Sources & evidence

ORD record
ord-d8e99cc22ae9474396133de3b0e872aa
Source dataset
uspto-grants-1999_11
Patent number
US05981558

Reaction notes

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