Benzoyl Peroxide → HCID 19611273, compound

HRID 1602360Notes

Reaction equation

HRID 1602360 reaction equation
[C:1]([O:4][CH2:5][C:6]1[O:7][C:8](=[O:12])[O:9][C:10]=1[CH3:11])(=[O:3])[CH3:2].[Br:13]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[C:1]([O:4][CH2:5][C:6]1[O:7][C:8](=[O:12])[O:9][C:10]=1[CH2:11][Br:13])(=[O:3])[CH3:2]

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 19611268HCID 19611268, compound

Product 1

HCID 19611273HCID 19611273, compoundYield 95%

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Conditions

Temperature
80 °C

Procedure

4-Acetoxymethyl-5-methyl-2-oxo-1,3-dioxolene (159 mg, 0.92 mmol) was dissolved in carbon tetrachloride (5.0 mL). Thereto were added N-bromosuccinimide (164 mg, 0.92 mmol) and benzoyl peroxide (11 mg, 0.046 mmol). This mixture was stirred at 80° C. for 1 hours. Through the ordinary post-treatment, crude Compound S-31 (220 mg, yield 95%) was obtained.

Workup

  1. custom(220 mg, yield 95%) was obtained

Sources & evidence

ORD record
ord-f072fe8a07954f2ab587aaff355ce561
Source dataset
uspto-grants-1999_11
Patent number
US05981558

Reaction notes

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