N-bromobutanimide → HCID 12661867, compound

HRID 1602389Notes

Reaction equation

HRID 1602389 reaction equation
[Cl:1][C:2]1[CH:3]=[CH:4][C:5]2[O:9][CH:8]=[CH:7][C:6]=2[C:10]=1[CH3:11].ClC1C(C)=CC2[O:20][CH:19]=[CH:18]C=2C=1.BrN1[C:28](=[O:29])[CH2:27]CC1=O>C(Cl)(Cl)(Cl)Cl.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>[Cl:1][C:2]1[CH:3]=[CH:4][C:5]([O:9][CH2:8][CH:7]([O:20][CH2:19][CH3:18])[O:29][CH2:28][CH3:27])=[CH:6][C:10]=1[CH3:11]

Participants

6

Reactant 3

HCID 67184N-bromobutanimideHCID 19611657HCID 19611657, compoundHCID 19611693HCID 19611693, compound

Product 1

HCID 12661867HCID 12661867, compound

Reagents, catalysts & solvents 2

HCID 7187Benzoyl PeroxideCatalystHCID 5943Carbon TetrachlorideSolvent

Procedure

A mixture of 5-chloro-4-methyl-benzofuran with 5-chloro-6-methyl-benzofuran (19.6 g), N-bromosuccinimide (23 g) and benzoyl peroxide (160 mg) in carbon tetrachloride (350 ml) was heated under reflux under a 200 W lamp for 36 h. The cooled mixture was filtered through hyflo and the filtrate evaporated to give the title compound as a dark oil (28.8 g)

Workup

  1. temperaturewas heated
  2. temperatureunder reflux under a 200 W lamp for 36 h
  3. filtrationThe cooled mixture was filtered through hyflo
  4. customthe filtrate evaporated

Sources & evidence

ORD record
ord-459037a00a7146f485631410de6030c2
Source dataset
uspto-grants-1999_11
Patent number
US05981572

Reaction notes

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