Sodium Hydroxide → Sodium bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate

HRID 1602557Notes

Reaction equation

HRID 1602557 reaction equation
[CH:1]12[CH2:7][CH:4]([CH:5]=[CH:6]1)[CH:3]([C:8]([OH:10])=[O:9])[CH:2]2[C:11]([OH:13])=[O:12].[OH-].[Na+:15]>O>[CH:1]12[CH2:7][CH:4]([CH:5]=[CH:6]1)[CH:3]([C:8]([O-:10])=[O:9])[CH:2]2[C:11]([O-:13])=[O:12].[Na+:15].[Na+:15]

Participants

4

Reactant 2

HCID 14798Sodium HydroxideHCID 979655-Norbornene-2,3-dicarboxylic acid

Product 1

HCID 21908873Sodium bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

To a suspension of norborn-5-en-2,3-dicarboxylic acid (5.01 g, 27.5 mmole) in H2O (50 mL) was added 1N aq. NaOH (55 mL, 55.0 mmol) at rt and the reaction mixture was stirred until a homogeneous solution was obtained. The solvent was removed in vacuo and the resulting colorless, crystalline product was dried: 5.57 g (90%), mp=385C.

Workup

  1. customwas obtained
  2. customThe solvent was removed in vacuo
  3. customthe resulting colorless, crystalline product was dried

Sources & evidence

ORD record
ord-33dad65e33df46859758870d3be19803
Source dataset
uspto-grants-1999_11
Patent number
US05981636

Reaction notes

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