Sodium Hydroxide → Sodium bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate

HRID 1602558Notes

Reaction equation

HRID 1602558 reaction equation
[CH:1]12[CH2:8][CH2:7][CH:4](C=[CH:6]1)[CH:3]1[C:9]([O:11][C:12](=[O:13])[CH:2]21)=[O:10].[OH-:14].[Na+:15]>CO>[CH:4]12[CH2:6][CH:1]([CH:8]=[CH:7]1)[CH:2]([C:12]([O-:11])=[O:13])[CH:3]2[C:9]([O-:10])=[O:14].[Na+:15].[Na+:15]

Participants

4

Reactant 2

HCID 14798Sodium HydroxideHCID 220977Bicyclo(2.2.2)oct-5-ene-2,3-dicarboxylic Anhydride

Product 1

HCID 21908873Sodium bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

To a suspension of bicyclo[2.2.2]-oct-5-en-2,3-dicarboxylic anhydride (2.01 g, 11.3 mmole) in MeOH (50 mL) was added 1 N aq. NaOH (22.4 mL, 22.4 mmol). The reaction mixture was stirred for 1 hour at room temperature. The solvent was removed in vacuo and the resulting colorless solid was dried: mp>400 C.

Workup

  1. customThe solvent was removed in vacuo
  2. customthe resulting colorless solid was dried

Sources & evidence

ORD record
ord-3086884fc7cc46d8a789281f457d109c
Source dataset
uspto-grants-1999_11
Patent number
US05981636

Reaction notes

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