HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-Nitrophenol → 1,3-Bis(3-nitrophenoxy)-5-trifluoromethylbenzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-Nitrophenol | HCID 11137 | — |
| Reactant | alpha,alpha,alpha-Trifluoro-3,5-dinitrotoluene | HCID 123060 | — |
| Product | 1,3-Bis(3-nitrophenoxy)-5-trifluoromethylbenzene | HCID 18692419 | — |
Reaction Steps
In an example of the process (i), 3,5-dinitrobenzotrifluoride is condensed with m-nitrophenol in the presence of a base, in an aprotic solvent, to give 1,3-bis(3-nitrophenoxy)-5-trifluoromethylbenzene, which is then reduced to 1,3-bis(3-aminophenoxy)-5-trifluoromethylbenzene, in a high yield.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05990261 |
| Source dataset | uspto-grants-1999_11 |
| ORD ID | ord-ee4172a1995349b9b5d718dd7832b325 |
| Source note | uspto-grants-1999_11 |