Tert-Butylamine → HCID 11142504, compound

HRID 1604124Notes

Reaction equation

HRID 1604124 reaction equation
[CH2:1]1[C:5]2[C:6]3[C:11]([C:12]4[CH:13]=[CH:14][CH:15]=[CH:16][C:17]=4[C:4]=2[CH:3]=[C:2]1[Si:18]([CH3:21])([CH3:20])Cl)=[CH:10][CH:9]=[CH:8][CH:7]=3.[C:22]([NH2:26])([CH3:25])([CH3:24])[CH3:23]>CCCCCC>[CH2:1]1[C:5]2[C:6]3[C:11]([C:12]4[CH:13]=[CH:14][CH:15]=[CH:16][C:17]=4[C:4]=2[CH:3]=[C:2]1[Si:18]([CH3:21])([CH3:20])[NH:26][C:22]([CH3:25])([CH3:24])[CH3:23])=[CH:10][CH:9]=[CH:8][CH:7]=3

Participants

4

Reactant 2

HCID 6385Tert-ButylamineHCID 23505024HCID 23505024, compound

Product 1

HCID 11142504HCID 11142504, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

To a 500 ml round bottom flask containing 1.98 g (0.0064 mole) of (1H-cyclopenta[1]phenanthrene-2-yl)dimethylchlorosilane and 250 ml of hexane was added 2.00 ml (0.0160 mole) of t-butylamine. The reaction mixture was allowed to stir for several days, then filtered using diatomaceous earth filter aid (Celite™), washed twice with hexane. The product was isolated by removing residual solvent under reduced pressure. The isolated yield was 1.98 g (88.9 percent).

Workup

  1. filtrationfiltered
  2. filtrationfilter aid (Celite™)
  3. washwashed twice with hexane
  4. customThe product was isolated
  5. customby removing residual solvent under reduced pressure

Sources & evidence

ORD record
ord-6dbb8074ec3049d5b69ab3b0c51a7d20
Source dataset
uspto-grants-1999_11
Patent number
US05993707

Reaction notes

Loading…