alpha-Pinene, (+)- → 164203-45-6

HRID 1604206Notes

Reaction equation

HRID 1604206 reaction equation
[CH2:1](/[C:3](=[CH:6]\[CH2:7][C@@H:8]1[CH2:12][CH:11]=[C:10]([CH3:13])[C:9]1([CH3:15])[CH3:14])/[CH:4]=[O:5])[CH3:2].CC1[C@@H]2C(C)(C)[C@@H](C2)CC=1>>[CH2:1](/[C:3](=[CH:6]\[CH2:7][C@@H:8]1[CH2:12][CH:11]=[C:10]([CH3:13])[C:9]1([CH3:14])[CH3:15])/[CH2:4][OH:5])[CH3:2]

Participants

3

Reactant 2

HCID 82227alpha-Pinene, (+)-HCID 86755498HCID 86755498, compound

Product 1

HCID 8030023164203-45-6

Procedure

(E)-(S)-2-Ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)-2-buten-1-al synthesized from (1R,5R)-α-pinene having an optical purity of 97% e.e. (available from Aldrich) was hydrogenated in the same manner as in Example 2 to obtain the title compound.

Sources & evidence

ORD record
ord-f83347d47fab4e08a1550db7d889e080
Source dataset
uspto-grants-1999_11
Patent number
US05994291

Reaction notes

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