1-Methylimidazole → HCID 178444699, compound

HRID 1604765Notes

Reaction equation

HRID 1604765 reaction equation
[CH3:1][N:2]1[CH:6]=[CH:5][N:4]=[CH:3]1.[Cl:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13]>>[Cl-:7].[CH2:8]([N+:4]1[CH:5]=[CH:6][N:2]([CH3:1])[CH:3]=1)[CH2:9][CH2:10][CH2:11][CH2:12][CH3:13]

Participants

3

Reactant 2

HCID 13901-MethylimidazoleHCID 109921-Chlorohexane

Product 1

HCID 178444699HCID 178444699, compound

Conditions

Temperature
100 °C

Procedure

Dry 1-methylimidazole (9.03 g, 0.11 mol) was mixed with 1-chlorohexane (12.06 g, 0.1 mol) and placed in a Corius tube inside a dry box. The Corius tube was then closed using a super seal in the dry box and sealed under vacuum. The two components formed two layers, inside the Corius tube, and this mixture was heated at 100° C. for a week. The resulting product was allowed to cool to room temperature when it formed a viscous product. The viscous product was transferred from the dry box to a Schlenk round bottomed flask where it was left under vacuum for 4 hours to form a viscous liquid.

Workup

  1. customplaced in a Corius tube inside a dry box
  2. customThe Corius tube was then closed
  3. customa super seal in the dry box
  4. customsealed under vacuum
  5. customThe two components formed two layers
  6. temperatureto cool to room temperature when it
  7. customformed a viscous product
  8. customThe viscous product was transferred from the dry box to a Schlenk round bottomed flask
  9. customto form a viscous liquid

Sources & evidence

ORD record
ord-d891116b02cd40cb96bf74461dfd1bd6
Source dataset
uspto-grants-1999_11
Patent number
US05994602

Reaction notes

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