Formic Acid → HCID 178484366, compound

HRID 1605024Notes

Reaction equation

HRID 1605024 reaction equation
[CH3:1][N:2]([CH3:8])[C:3](=[NH:7])[N:4]([CH3:6])[CH3:5].[CH:9]([OH:11])=[O:10]>CCOCC>[CH:9]([O-:11])=[O:10].[CH3:1][N:2]([CH3:8])[C:3](=[NH2+:7])[N:4]([CH3:6])[CH3:5]

Participants

4

Reactant 2

HCID 284Formic AcidHCID 664601,1,3,3-Tetramethylguanidine

Product 1

HCID 178484366HCID 178484366, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent2×

Procedure

Tetramethylguanidine (22 g., 0.19 mole) was dissolved in anhydrous ether (100 ml.) and to this solution at 0° was added a solution of anhydrous formic acid (7.1 ml., 0.198 mole) in anhydrous ether (40 ml.). The resulting salt crystallized. It was collected, washed with ether, dried in high vacuum and recrystallized from chloroform-ether.

Workup

  1. customThe resulting salt crystallized
  2. customIt was collected
  3. washwashed with ether
  4. customdried in high vacuum
  5. customrecrystallized from chloroform-ether

Sources & evidence

ORD record
ord-955a2edaee774b559658155b74868ef6
Source dataset
uspto-grants-1976_04
Patent number
US03948927

Reaction notes

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