Boron tribromide → HCID 21549171, compound

HRID 1605113Notes

Reaction equation

[Cl:1][C:2]1([Cl:15])[C:4]([CH3:6])([CH3:5])[CH:3]1[C:7]1[CH:12]=[CH:11][C:10]([O:13]C)=[CH:9][CH:8]=1.B(Br)(Br)Br>>[Cl:1][C:2]1([Cl:15])[C:4]([CH3:6])([CH3:5])[CH:3]1[C:7]1[CH:8]=[CH:9][C:10]([OH:13])=[CH:11][CH:12]=1

Participants

Reactant 2

HCID 25134Boron tribromide

HCID 21549140HCID 21549140, compound

Product 1

HCID 21549171HCID 21549171, compound

Procedure

p-(2,2-Dichloro-3,3-dimethylcyclopropyl)phenol was prepared from 65.8 g. of p-(2,2-dichloro-3,3-dimethylcyclopropyl)anisole and 37.5 g. of boron tribromide according to the procedure described above in Example 1, part (c). There was thus obtained 23.5 g. of p-(2,2-dichloro-3,3-dimethylcyclopropyl)phenol, m.p. 111°-111.5°C. when recrystallized from a benzene-hexane mixture.

Workup

customof p-(2,2-dichloro-3,3-dimethylcyclopropyl)phenol, m.p. 111°-111.5°C. when recrystallized from a benzene-hexane mixture

Sources & evidence

ORD record: ord-8216fbd384a14f02bf66430727b93b9c
Source dataset: uspto-grants-1976_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03948973

Reaction notes

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