Hydrogen Peroxide → Diisopropyl peroxydicarbonate

HRID 1605408Notes

Reaction equation

Cl[C:2]([O:4][CH:5]([CH3:7])[CH3:6])=[O:3].[OH:8][OH:9].[OH-:10].[Na+].[Na+].[Cl-]>>[CH:5]([O:4][C:2]([O:8][O:9][C:2]([O:4][CH:5]([CH3:7])[CH3:6])=[O:10])=[O:3])([CH3:7])[CH3:6]

Participants

Reactant 4

HCID 784Hydrogen Peroxide

HCID 5234Sodium Chloride

HCID 7917Isopropyl chloroformate

HCID 14798Sodium Hydroxide

Product 1

HCID 7769Diisopropyl peroxydicarbonate

Procedure

Following the Example II procedure, IPP is prepared at the rate of 50 pph in an average assay of greater than 98% from 85 pph of isopropyl chloroformate, 28.5 pph of 50% H2O2, 160 pph of 20% NaOH and 50 pph of saturated NaCl solution.

Sources & evidence

ORD record: ord-d397ba3176cd4d4c93f80642c24a081c
Source dataset: uspto-grants-1976_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03950375

Reaction notes

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